dc.contributor.advisor Jeffrey C. Grossman en_US
dc.contributor.author Tomasik, Michelle Ruth en_US
dc.contributor.other Massachusetts Institute of Technology. Department of Physics. en_US
dc.date.accessioned 2015-10-14T15:03:22Z
dc.date.available 2015-10-14T15:03:22Z
dc.date.copyright 2015 en_US
dc.date.issued 2015 en_US
dc.identifier.uri http://hdl.handle.net/1721.1/99287
dc.description Thesis: Ph. D., Massachusetts Institute of Technology, Department of Physics, 2015. en_US
dc.description Cataloged from PDF version of thesis. en_US
dc.description Includes bibliographical references (pages 115-124). en_US
dc.description.abstract Our work was inspired by the need to improve the efficiency of new types of solar cells. We mainly focus on metal-semiconductor interfaces. In the CdSe study, we find that not all surface states serve to pin the Fermi energy. In our organic-metal work, we explore the complexity and challenges of modeling these systems. For example, we confirm that aromatic compounds indeed have stronger interactions with metal surfaces, but this may lead to the geometry changing as a result of the interaction. We also find that molecules that are not rigid are strongly affected by their neighboring molecules. Surface roughness will have an effect on molecules that more strongly bind to metal surfaces. This study of interfaces relates to one part of the picture of efficiency, but we also look at trying to go beyond the Shockley-Quiesser limit. We explore the idea of combining a direct and indirect bandgap in a single material but find that, in quasi-equilibrium, this does no better than just the direct gap material. This thesis hopes to extend our understanding of metal-semiconductor interface behavior and lead to improvements in photovoltaic efficiency in the future. en_US
dc.description.statementofresponsibility by Michelle Ruth Tomasik. en_US
dc.format.extent 124 pages en_US
dc.language.iso eng en_US
dc.publisher Massachusetts Institute of Technology en_US
dc.rights M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. en_US
dc.rights.uri http://dspace.mit.edu/handle/1721.1/7582 en_US
dc.subject Physics. en_US
dc.title Theoretical investigation of energy alignment at metal/semiconductor interfaces for solar photovoltaic applications en_US
dc.type Thesis en_US
dc.description.degree Ph. D. en_US
dc.contributor.department Massachusetts Institute of Technology. Department of Physics. en_US
dc.identifier.oclc 922886248 en_US
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